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What is the structure of an atom?

 Structure of atom is currently based on bohr and rutherfold models

Rutherfold’s planetary model of atom (also called the nuclear model of atom)



Ernst Rutherford (1871–1937), a former research student of J. J. Thomson, was engaged in experiments on α-particles emitted by some radioactive elements. In 1906, he proposed a classic experiment of scattering of these α-particles by atoms to investigate the atomic structure. This experiment was later performed around 1911 by Hans Geiger (1882–1945) and Ernst Marsden (1889–1970), who was 20 year student.       The entire model was based on experiment that is known as Rutherfold’s Alpha-particle scattering experiment (CLICK HERE to know more)

Key points of this model

* Rutherford’s experiments suggested the size of the nucleus to be about 10–15 m to 10–14 m. From kinetic theory, the size of an atom was known to be 10–10 m, about 10,000 to 100,000 times larger than the size of the nucleus.

*the mass and positive charge of the atom is concentrated in a small volume. 

* The electrons would seem to be at a distance from the nucleus of about 10,000 to 100,000 times the size of the nucleus itself. Thus, most of an atom is empty space

*The Rutherford nuclear model of the atom which involves classical concepts, pictures the atom as an electrically neutral sphere consisting of a very small, massive and positively charged nucleus at the centre surrounded by the revolving electrons in their respective dynamically stable orbits. 



BOHR MODEL OF THE HYDROGEN ATOM



Niels Bohr studied in Rutherford’s laboratory for several months in 1912 and he was convinced about the validity of Rutherford nuclear model.

i) Bohr’s first postulate was that an electron in an atom could revolve in certain stable orbits without the emission of radiant energy, contrary to the predictions of electromagnetic theory. According to this postulate, each atom has certain definite stable states in which it can exist, and each possible state has definite total energy. These are called the stationary states of the atom.

(ii) Bohr’s second postulate defines these stable orbits. This postulate states that the electron revolves around the nucleus only in those orbits for which the angular momentum is some integral multiple of h/2Ï€ where h is the Planck’s constant (= 6.6 × 10–34 J s). Thus the angular momentum (L) of the orbiting electron is quantised. That is L = nh/2Ï€ 

(iii) Bohr’s third postulate incorporated into atomic theory the early quantum concepts that had been developed by Planck and Einstein. It states that an electron might make a transition from one of its specified non-radiating orbits to another of lower energy. When it does so, a photon is emitted having energy equal to the energy difference between the initial and final states. The frequency of the emitted photon is then given by hν= Ei–Ef (12.12) ,where Ei and Ef are the energies of the initial and final states and Ei > Ef .






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